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Table of contents
Introduction
Acronyms and Abbreviations
Chapter I. From polymers and supramolecular chemistry to supramolecular polymers
1. Polymers
2. Supramolecular chemistry
3. Supramolecular polymers
Chapter II. Synthesis of supramolecular polymers by grafting of Thy and DAT stickers on telechelic PPO chains
1. Telechelic PPO chains as spacers between the stickers
2. Grafting DAT sticker
3. Grafting Thy sticker
4. Blending Thy-PPO-X-Thy with DAT-PPO-X-DAT
5. Heteroditopic grafting of Thy and DAT (grafting Thy on one side and DAT on the other side)
Chapter III. Supramolecular polymers in solution: solvent dependent behavior
1. Supramolecular polymers in solution
2. Supramolecular polymers act as bolaamphiphiles in a dissociative solvent
3. Supramolecular polymers are associated in a non-dissociative solvent
4. Conclusions and perspectives
Chapter IV. Order and disorder in bulk supramolecular polymers.
1. Order-disorder transition in supramolecular polymers
2. Disorder in supramolecular polymers
3. Suppression of mesoscopic order by complementary interactions in supramolecular polymers
Chapter V. Glass transition of supramolecular polymers in the bulk
General Conclusion
Appendix I. Material and methods
Appendix II. Synthesis and characterization
Appendix III. Résumé en français
Acknowledgements
