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Table of contents
PART I: BIBLIOGRAPHY
1. Adsorption
1.1. Definition and types of adsorption
1.2. Adsorption of organic pollutants
1.3. Current stage and future prospects
2. Electrosorption
2.1. Electrosorption: background and principle
2.2. Influence of the main parameters
2.3. Reactor design
2.4. Factors influencing the electrodesorption step
2.5. Long-term efficiency of electrosorption
2.6. Modeling
2.7. Current developments and future prospects
PART II: MATERIAL AND METHODS
1. Adsorption
1.1. Sample collection and characterization
1.2. Preparation of activated carbon
1.3. Preparation of the beads
1.4. Characterization of beads and GAC
1.5. Stirred batch and column sorption experiments
1.6. Batch and fixed-bed column data analysis
1.7. Analytical methods
2. Electrosorption
2.1. Effluents preparation and characterization
2.2. Preparation and characterization of the 3D porous electrode
2.3. Electrochemical setup and procedure
2.4. Electrochemical regeneration of the GAC electrode
2.5. Electrochemical degradation of OMWW
PART III: RESULTS AND DISCUSSIONS
CHAPTER I: COMPOSITE BEADS
I. Performance and dynamic modeling of a continuously operated pomace olive packed-bed for olive mill wastewater treatment and phenol recovery
1. Introduction
2. Results and discussion
2.1. Physicochemical properties of the effluent
2.2. Characterization of the adsorbent
2.3. Adsorption efficiency
3. Conclusions
II. Electrosorption of phenolic compounds from olive mill wastewater: mass transport consideration under transient regime through alginate-activated carbon fixed-bed electrode
1. Introduction
2. Modeling
3. Results and discussion
3.1. Electrochemical characterization of the 3D porous electrodes
3.2. Electrosorption efficiency
4. Conclusions
CHAPTER II: GRANULAR ACTIVATED CARBON
I. Granular activated carbon based on pomace olive for olive mill wastewater treatment and phenol recovery
1. Introduction
2. Results and discussion
2.1. Physicochemical properties of effluent
2.2. Preparation and characterization of GAC
2.3. Adsorption efficiency
2.3.1. Adsorption equilibrium study
2.3.2. Modeling of adsorption kinetics
2.3.3. Effect of pH
2.3.4. Effect of temperature
2.3.5. Fixed-bed column
2.4. Desorption
3. Conclusions
References
II. Electrosorption with bio-sourced granular activated carbon electrode for phenols recovery and combination with electrooxidation for residual olive mill wastewater treatment
1. Introduction
2. Results and discussion
2.1. Characterization of GAC
2.1.1. Influence of electrochemical conditioning on GAC characteristics
2.1.2. Electrochemical characterization of the conditioned GAC
2.2. Electrosorption
2.2.1. Phenol electrosorption
2.2.2. Effect of phenolic compounds properties
2.2.3. OMWW electrosorption
2.3. Electrochemical regeneration of the GAC electrode
2.4. Electrochemical degradation of OMWW
3. Conclusions
References




