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Table of contents
General Introduction
I Context and Objectives
I.1 Wastewater reuse in irrigation
I.1.1 Context and issues related to the reuse of treated wastewater
I.1.2 Worldwide application of wastewater in irrigation
I.1.3 Wastewater
I.1.4 Water treatment in a Wastewater Treatment Plant (WWTP)
I.1.5 Beneficial and negative impacts of the reuse of treated wastewater for agricultural irrigation
I.2 Irrigation generalities
I.2.1 Irrigation systems
I.2.2 Clogging problems in micro-irrigation systems
I.2.3 Types of drippers
I.2.4 Hydrodynamics and flow behavior of drippers
I.2.5 Parameters influencing clogging in micro-irrigation
I.3 Biofilm
I.3.1 Definition of Biofilm
I.3.2 Advantages and disadvantage of biofilms development
I.3.3 The different stages of biofilm development
I.3.4 Factors influencing the different stages of biofilm development in micro-irrigation systems
I.4 Characterization of chemical and biological clogging
Conclusion and thesis objectives
II Materials and Methods
Introduction
II.1 Characterization of chemical precipitation
II.1.1 Chemical precipitation in batch reactors
II.1.2 Precipitation modeling with PHREEQC
II.2 Effect of shear stress on biofilm development
II.2.1 Taylor-Couette Reactor generalities
II.2.2 Hydrodynamic conditions inside TCR
II.2.3 Choice of the shear stress
II.2.4 TCR speed rotation and parameters
II.2.5 TCR experimental set-up
II.2.6 Experimental protocol
II.2.7 Wastewater Treatment Plant (WWTP) of Mauguio
II.2.8 Analyzing the water quality inside the TCR
II.3 Effect of calcium carbonate on biofilm development
II.3.1 Experimental set-up
II.3.2 Method of fouling analysis
II.3.3 Synthetic effluent quality
II.3.4 Characterization of the fouling material
III Characterization of chemical precipitation
Introduction
III.1 Experimental characterization
III.1.1 Chemical precipitation
III.1.2 Precipitate characterization by X-ray diffraction (XRD)
III.1.3 Precipitate characterization by thermogravimetric analysis (TGA)
III.1.4 Effect of pH and temperature on calcium carbonate precipitation
III.2 Numerical characterization
III.2.1 Treated wastewater speciation
III.2.2 Calcite saturation index in function of pH and temperature
III.2.3 Experimental and numerical calculation of pH and SI
III.2.4 Numerical precipitation of calcite
III.2.5 Effect of CO2 partial pressure on calcite precipitation
Conclusion
IV Characterization of biological fouling
Introduction
IV.1 Effect of shear stress on biofilm development
IV.1.1 Validation of the protocol for monitoring the biofilm development kinetics
IV.1.2 Evolution of the fouling in the TCR
IV.1.3 Characterization of fouling chemical composition inside the TCR
IV.1.4 Conclusion
IV.2 Effect of calcium carbonate precipitation
IV.2.1 Interaction between calcium carbonate precipitation and biofilm development in irrigation
pipes
IV.2.2 Characterization of the fouling by DRX and TGA
IV.2.3 Effect of calcium carbonate precipitation on biofilm development and dripper clogging
IV.2.4 Conclusion
Conclusion
List of Figures
List of Tables
References



